Basic Chemistry

Chapter 1 Introduction
1．1 Introduction to Chemistry
1．2 Measurement and S] Units
1．3 Ways of Expressing Concentration
1．4 Names and Symbols of the Elements
1．5 Nomenclature of Inorganic Compounds
Summary
Essay： The Human Genome Project
Problems

Chapter 2 Colligative Properties of Solutions
2．1 Vapor Pressure of a Solution
2．2 Boiling Point Elevation
2．3 Freezing Point Depression
2．4 Osmosis and Osmotic Pressure of Solutions
Summary
Essay： The Artificial Kidney——A Hemodialysis Machine
Problems

Chapter 3 Electrolyte Solutions
3．1 Strong Electrolytic Solutions
3．2 Bronsted-Lowry Acid-Base Theory
3．3 Solving Problems Involving Acid-Base Equilibrium
3．4 Electron-Pair Donation and the Lewis Acid-Base Definition
3．5 Equilibria of Slightly Soluble Ionic Compounds
Summary
Essay： Aspirin and Digestion
Problems

Chapter 4 Buffer Solutions
4．1 Composition and Action of Buffer Solutions
4．2 The Henderson-Hasselbalch Equation
4．3 Buffer Capacity and Buffer Range
4．4 Preparing a Buffer
4．5 Buffers Action in Human Blood
Summary
Essay： Acidosis and Alkalosis
Problems

Chapter 5 Colloids
5．1 Colloid and Its Basic Behaviors
5．2 Sol
5．3 Macromolecules
5．4 Surface Active Agent and Emulsions
Summary
Essay： Colloids in Water Purification
Problems

Chapter 6 Thermochemistry and Thermodynamics
6．1 Some Basic Definitions
6．2 The Law of Energy Conservation
6．3 Spontaneous Change： Entropy and Gibbs Free Energy
6．4 The Dynamic Nature of the Equilibrium State
Summary
Essay： The Universal RoleofATP
Problems

Chapter 7 Kinetics： Rates and Mechanisms of Chemical Reactions
7．1 Expression of the Reaction Rate
7．2 Reaction Mechanisms： Steps in the Overall Reaction
7．3 Integrated Rate Laws： Concentration Changes Over Time
7．4 Collision and Transition State Theories
7．5 The Effect of Temperature on Reaction Rate
7．6 Catalysis： Speeding Up a Chemical Reaction
Summary
Essay： Protease Inhibitor and AIDS
Problems

Chapter 8 Electrochemistry： Chemical Change and ElectricaIWork
8．1 Oxidation-Reduction Reactions
8．2 Voltaic Cells： Using Spontaneous Reactions to Generate Electric Energy．．．
8．3 Cell Electromotive Force （emf） and Free Energy
8．4 Concentration Effects on Cell Potential and the Nemst Equation
8．5 Determination ofpH
8．6 Electrochemistry and Biosensors
Summary
Essay： Heartbeats and Electrocardiography
Problems

Chapter 9 Atomic Structure and the Periodic Table
9．1 Structure of the Hydrogen Atom
9．2 Wave Function and the Atomic Orbital
9．3 Electron Configurations and the Periodic Table
9．4 Trends in Some Key Periodic Atomic Properties
9．5 Importance of Metallic and Nonmetallic Elements for Human Health
Summary
Essay： Nuclear Spin and Magnetic Resonance Imaging
Problems

Chapter 10 Molecular Structure
10．1 The Covalent Bond Model
10．2 HybridizationofAtomic Orbitals
10．3 Valence Shell Electron Pair Repulsion （VSEPR） Theory and Molecular Shape．
10．4 Molecular Orbital （MO） Theory
10．5 Intermolecular Forces
Summary
Essay： Molecular Shape， Biological Receptors， and the Sense of Smell
Problems

Chapter 11 Coordination Complexes
11．1 Basic Concepts of Complexes
11．2 Theoretical Basis for the Bonding and Properties of Complexes
11．3 Equilibrium Involving Complex Ions
11．4 Chelates and Living Ligands
11．5 Applications of Coordination Complexes
Summary
Essay： The Cooperative Release of Oxygen from Oxyhemoglobin
Problems

Chapter 12 Titrimetric Methods of Analysis
12．1 Overview of Titrimetry
12．2 Uncertainty in Measurement and Significant Figures
12．3 Titrations Based on Acid-Base Reactions
12．4 Titrations Based on Redox Reactions
12．5 Titrations Based on Complexation Reactions
12．6 Precipitation Titrations
Summary
Essay： Analytical Chemistry and Public Perceptions of Toxicity
Problems

Chapter 13 Ultraviolet Visible Spectrophotometry
13．1 Absorption Spectrum
13．2 Quantitative Calculations
13．3 Visible Spectruphotometry
13．4 Methods to Improve Sensitivity and Accuracy
13．5 Introduction to UV Spectruphotometry
Summary
Essay： Clinical Applications of Ultraviolet-Visible Molecular Absorption
Problems

Chapter 14 Introduction to Modern Instrumental Analysis
14．1 Atomic Absorption Spectroscopy
14．2 Molecular Fluorescence Spectroscopy
14．3 Chromatography：
Summary
Essay： Applicationsi0f Gas Chromatography
Problems
Index
Appendix
References