光物理基础

Chapter 1 Light Absorption 1.1 Introduction to Photochemistry and Photophysics 1.1.1 Photochemistry and Photophysics in Nature 1.1.2 TheNature of Light 1.1.3 Definition of Photophysics and Photochemistry 1.1.4 Development of Photophysics and Photochemistry 1.2 Light Absorption 1.2.1 Basic Concepts of Light Absorption 1.2.2 Electronically Excited States 1.2.3 Fundamental Principles of Light Absorption 1.2.4 Spin Multiplicity 1.2.5 Selection Rules for Light Absorption 1.2.6 Absorption Spectrum References Chapter 2 Deactivation of Excited States 2.1 Brief Introduction to Deactivation of Excited States 2.2 The Jablonski Diagram 2.3 Intramolecular Processes 2 3 1 Non-radiative Transitions 2 3 2 Radiative Transitions 2.4 Intermolecular Processes 2 4 1 Vibrational Relaxation 2.4.2 Energy Transfer 2 4 3 Electron Transfer 2.5 Dynamics of Excited State Deactivation References Chapter 3 Fluorescence and PhosDhorescence 3.1 Introduction to Fluorescence 3.1.1 Luminescence in Nature 3.1 2 History of Fluorescence 3.1.3 Fluorescence Processes 3.1.4 Types of Fluorescence 3.2 Fluorescence Spectroscopy 3.2.1 Absorption Spectrum 3.2.2 Excitation Spectrum 3.2.3 Emission Spectrum 3.3 Several Rules about Fluorescence 3.3.1 Kasha's Rule 3.3.2 Miorqmage Rule 3.3.3 The Stokes Shift 3.4 Fluorescence Features 3.4.1 Fluorescence Lifetime 3.4.2 QuantumYield 3.4.3 Fluorescence Intensity 3.4.4 Fluorescence Polarization 3.5 Factors Affecting Fluorescence 3.5.1 Effect ofthe Molecular Structure 3.5.2 Effjcc ofthe Environment 3.6 Phosphorescence 3.6 1 Definition of Phosphorescence