- ISBN:9787302631125
- 装帧:精装
- 册数:暂无
- 重量:暂无
- 开本:其他
- 页数:232
- 出版时间:2023-11-01
- 条形码:9787302631125 ; 978-7-302-63112-5
本书特色
《几种新型含氧燃料的燃烧反应动力学研究(英文版)》针对几类新型含氧燃料,选取其中具有代表性的典型化合物,开展燃烧反应动力学研究,在此基础上发展了经过验证的具有良好预测性能的燃烧反应动力学模型,可为从事含氧燃料燃烧反应动力学研究的相关科研人员提供参考。
内容简介
《几种新型含氧燃料的燃烧反应动力学研究(英文版)》针对几类新型含氧燃料—碳酸酯类、酮类和多醚类等,选取其中具有代表性的典型化合物,包括碳酸二甲酯、碳酸二乙酯、环戊酮、3-戊酮、乙二醇二甲醚和二甲氧基甲烷,开展燃烧反应动力学研究。实验方面,选取合适的诊断方法测量了目标燃料在不同工况下详细的组份信息;动力学模型方面,通过高精度理论计算获取了关键基元反应的速率常数,在此基础上发展了经过验证的具有良好预测性能的燃烧反应动力学模型。《几种新型含氧燃料的燃烧反应动力学研究(英文版)》可为从事含氧燃料燃烧反应动力学研究的相关科研人员提供参考。
目录
1.1Background
1.1.1The significance of biofuels to energy, climate and environment
1.1.2Novel oxygenated fuels and emission tests in engines
1.1.3Kinetic studies on the combustion of oxygenated fuels
1.2The object of this book and relevant research in literature
1.2.1Research objects
1.2.2Status of related research
1.3The research content and chapter arrangement of this book Chapter 2Experimental, kinetic modeling and theoretical methods
2.1Experimental methods
2.1.1The low-pressure laminar premixed flame experimental set-ups
2.1.2The flow-tube reactor pyrolysis experimental set-up
2.1.3The jet-stirred reactor (JSR) oxidation experimental set-up
2.2Kinetic modeling methods
2.2.1Construction of kinetic reaction mechanism
2.2.2Thermodynamics and transportation parameter acquisition
2.2.3Kinetic simulation method
2.3Theoretical calculation method
2.3.1Ionization energies calculation
2.3.2Rate coefficients calculation Chapter 3High-temperature combustion kinetics of carbonate ester and ketone fuels
3.1Introduction
3.2The high-temperature oxidation and pyrolysis kinetics of dimethyl carbonate
3.2.1Kinetic model development
3.2.2DMC pyrolysis in a flow tube
3.2.3Low-pressure laminar premixed flames of DMC
3.2.4Comprehensive validations of the kinetic model
3.3The high-temperature oxidation and pyrolysis kinetics of diethyl carbonate
3.3.1Kinetic model development
3.3.2DEC pyrolysis in a flow tube
3.3.3Laminar premixed flames of DEC
3.4Comparison of combustion characteristics of DMC and DEC
3.5Experimental and kinetic modeling study of low-pressure premixed flames fueled by two C5 ketones
3.5.1Kinetic model development
3.5.2Fuel consumptions and primary intermediates formation
3.5.3Formation of pollutant precursors
3.6Summary Chapter 4The low temperature oxidation kinetics of polyether fuels
4.1Introduction
4.2Low-temperature oxidation kinetics of 1,2-dimethoxyethane (1,2-DME)
4.2.1Experimental condition
4.2.2Kinetic model development
4.2.3JSR low-temperature oxidation of ethylene glycol dimethyl ether
4.2.4Model validation under premixed flame conditions
4.3Low-temperature oxidation kinetics of dimethoxymethane (DMM)
4.3.1Experimental conditions
4.3.2Kinetic model development
4.3.3Low-temperature oxidation reactivity and species formation
4.4Summary Chapter 5The blending effects of oxygenated additives under premixed flame conditions
5.1Introduction
5.2Experimental conditions
5.3Premixed flames fueled by ethane and DMM (or DMC) blends
5.3.1Model construction and validation
5.3.2Results and discussion
5.4Premixed flames fueled by benzene and ethanol (or DME) blends
5.4.1Kinetic model development
5.4.2Results and discussion
5.5Summary Chapter 6Conclusions and perspectives
6.1Major conclusions
6.2Main innovations
6.3Perspectives References Appendix ANomenclature of species involved in low-temperature oxidation of polyether fuels Appendix BChemical structures of the premixed flames fueled by binary fuels used for model validation Acknowledgements
作者简介
孙雯禹博士于2018年7月获清华大学工学博士学位,目前在法国国家科学研究中心从事博士后研究工作,研究方向为燃烧反应动力学。孙雯禹博士在国际权威期刊上发表研究论文二十余篇,并于2018年获得由国际燃烧学会颁发的Bernard Lewis Fellowship,该奖项为鼓励燃烧科学领域的青年学者而设立,每两年颁发给全球范围内不超过6名青年学者。
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