化学类专业实验(双语版)(宋广亮)

**章化学实验室基础知识1

第二章实验部分16
实验一溶胶-凝胶法制备纳米二氧化钛16
Experiment 1Preparation of Nano-TiO2 by Sol-Gel Method17
实验二XRD分析纳米二氧化钛的晶相20
Experiment 2Phase characterization of Nano-TiO2 powder by XRD22
实验三纳米二氧化钛光催化降解染料25
Experiment 3Photocatalytic degradation of dyes by Nano-TiO227
实验四乙酰二茂铁的制备29
Experiment 4Preparation of Acetylferrocene32
实验五乙酰二茂铁粗产物的重结晶及红外光谱测定36
Experiment 5Recrystallization of crude products of acetylferrocene and its characterization by infrared spectroscopy38
实验六乙酰二茂铁的熔点和1H NMR测定41
Experiment 6Determination of melting point and 1H NMR of ferrocene43
实验七聚苯胺的电化学合成46
Experiment 7Electrosynthesis of Polyaniline48
实验八聚苯胺导电聚合物膜的pH响应50
Experiment 8pH response of polyaniline conductive polymer film51
实验九2-氨基-1，3，4-噻二唑的制备53
Experiment 9Synthesis of 2-amino-1，3，4-thiadiazole54
实验十反相离子对色谱法分析2-氨基-1，3，4噻二唑的含量56
Experiment 10Ion pair reversed phaser chromatographic separation and quantitation of 2-amino-1，3，4-thiadiazole59
实验十一聚丙烯酸合成63
Experiment 11Synthesis of Polyacrylic acid65
实验十二黏度法测定水溶性高聚物的平均分子量68
Experiment 12Determination of the average relative molecular weight of water-soluble polymer by viscosity method73
实验十三酶催化分光光度法测定过氧化氢80
Experiment 13Determination of hydrogen peroxide by enzyme catalytic spectrophotometry82
实验十四磷酸的电位滴定84
Experiment 14Potentiometric titration of phosphoric acid86
实验十五对乙酰氨基酚的电化学反应机理及其浓度的测定89
Experiment 15Study on the electrochemical reaction mechanism of acetaminophen and determination of its concentration91
实验十六ZnS:Mn纳米荧光材料的合成及其光学性质研究95
Experiment 16Synthesis and optical properties of ZnS:Mn fluorescent nanomaterials97
实验十七8-羟基喹啉铝的合成和荧光性能表征99
Experiment 17Synthesis and fluorescence characterization of 8-hydroxyquinoline aluminum102
实验十八有机螺环染料的荧光特性及其定量分析106
Experiment 18Fluorescence characteristics and quantitative analysis of organic spiro dyes110
实验十九离子液体bmimBF4的制备114
Experiment 19Synthesis of the ionic liquid bmimBF4116
实验二十柠檬精油的提取117
Experiment 20Extraction of lemon essential oil119
实验二十一柠檬精油的GC-MS分析120
Experiment 21GC-MS analysis of lemon essential oil122
实验二十二钛硅分子筛的合成123
Experiment 22Synthesis of titanium silicalite molecular sieve（TS-1）126
实验二十三钛硅分子筛的表征（SEM）129
Experiment 23Characterization of titanium silicalite molecular sieve TS-1(SEM)131
实验二十四钛硅分子筛催化苯酚制备苯二酚134
Experiment 24Preparation of hydroquinone from phenol catalyzed by titanium silicalite molecular sieve137

附录141
附录一X射线衍射仪操作规程141
附录二SEM使用操作流程142
附录三Agilent 7890B/5977A气质联用仪操作规程143
附录四高效液相色谱仪器操作规程146
附录五电极的使用说明150
附录六奥立龙CHN060型酸度计的操作规程151
附录七显微熔点仪操作规程151
附录八CHI 660电化学工作站操作规程152
附录九Bruker 400MHz核磁共振谱仪操作规程153
附录十FluoroMax-4荧光光谱仪操作规程156

参考文献159