逸出气体分析(第二版)

第1章 逸出气体分析简介 Introduction to Evolved Gas Analysis(1)

第2章 热重-质谱联用技术TGA-MS(6)

2.1质谱的原理 Principles of MS(6)

2.2TGA-MS 测量系统 The TGA-MS System(8)

2.3测量模式 Measurement Modes(9)

2.4结果解释 Interpretation of Results(11)

2.5典型的碎片化模式 Typical Fragmentation Patterns(15)

2.6结果表述 Presentation of Results(16)

第3章 热重-红外光谱联用技术TGA-FTIR (17)

3.1FTIR的原理 Principles of FTIR(17)

3.2TGA-FTIR系统 The TGA-FTIR System(21)

3.3曲线表示 Presentation of Results(22)

3.4解析方法 Interpretation Procedure(24)

3.5光谱的解析 Interpretation of Spectra(26)

3.6特征吸收频率 Characteristic Absorption Frequencies(27)

3.7结果表述 Presentation of Results(29)

第4章 热重分析-气相色谱/质谱联用技术TGA-GC/MS (30)

4.1GC的原理 Principles of GC(30)

4.2TGA-GC/MS系统 The TGA-GC/MS System(35)

4.3测量可行性 Measurement Possibilities(36)

4.4测量结果 Results(39)

第5章 热重分析-微型气相色谱/质谱联用技术TGA-Micro GC/MS (41)

5.1微型气相色谱仪的原理 Principles of Micro GC(41)

5.2TGA-Micro GC和TGA-Micro GC/MS系统

TGA-Micro GC and TGA-Micro GC/MS Systems(44)

5.3实验结果 Results(45)

第6章 应用简介 Introduction to the Applications (46)

第7章应用介绍 Applications List (49)

7.1通过TGA-MS、TGA-FTIR和TGA-MicroGC研究一水合草酸钙的分解机理

Decomposition of Calcium Oxalate Monohydrate (Tutorial) by TGA-MS,

TGA-FTIR and TGA-Micro GC(55)

7.2通过TGA-MS和TGA-FTIR研究五水合硫酸铜的分解机理

Decomposition of Copper Sulfate Pentahydrate (Tutorial)

by TGA-MS and TGA-FTIR(57)

7.3实验条件对MS灵敏度的影响分析

Influence of Experimental Conditions on MS Sensitivity(59)

7.4通过TGA-MS和TGA-GC/MS多次进样法研究乙酰水杨酸的分解

Decomposition of Acetylsalicylic Acid by TGA-MS and TGA-GC/MS Multi-injection(65)

7.5通过TGA-FTIR研究BHET的热降解

Thermal Degradation of BHET by TGA-FTIR(67)

7.6通过TGA-FTIR研究工业月桂醇的分解

Decomposition of Technical Lauryl Alcohol by TGA-FTIR(70)

7.7通过TGA-MS检测药物中的残留溶剂

Detection of Residual Solvents in a Pharmaceutical Substance by TGA-MS(72)

7.8通过TGA-MS研究填充有机物的沸石的解吸附

Desorption of a Zeolite Filled with Organic Matter by TGA-MS(73)

7.9通过TGA-MS研究PVC粉末的热裂解

Pyrolysis of PVC Powder by TGA-MS(76)

7.10通过TGA-FTIR研究氟化电缆线

Investigation of Fluorinated Cable Wires by TGA-FTIR(78)

7.11通过TGA-MS检测橡胶样品中的水杨酸甲酯

Detection of Methyl Salicylate in a Rubber Sample by TGA-MS(80)

7.12通过TGA-FTIR研究有机硅聚合物的降解

Degradation of a Silicone Polymer by TGA-FTIR(81)

7.13通过TGA-MS和TGA-FTIR研究氨基树脂的固化和分解

Curing and Decomposition of an Amino Resin by TGA-MS and TGA-FTIR(83)

7.14通过TGA-FTIR和DSC研究热转变和分解以鉴别BR和NR橡胶

Identification of BR and NR Rubbers. Study of Thermal Transitions and Decomposition

by TGA-FTIR and DSC(85)

7.15通过TMA-MS研究印刷电路板的分层

Delamination of Printed Circuit Boards by TMA-MS(88)

7.16通过TMA-MS研究用于封装发泡剂的聚合物的膨胀和分解

Expansion and Decomposition of a Polymer Used To Encapsulate a Blowing Agent

by TMA-MS(89)

7.17通过TGA-MS测定离子液体中的水分含量

Determination of the Water Content of an Ionic Liquid by TGA-MS(91)

7.18通过TGA-FTIR研究热裂解并阐明阻燃机理

From the Investigation of Pyrolysis to the Elucidation of Fire Retardancy Mechanisms

by TGA-FTIR(93)

7.19通过TGA-MS和DSC研究高熔点陶瓷

High Melting Ceramics by TGA-MS and DSC(97)

7.20通过TGA-MS和显微DSC研究唑来膦酸水合物的热行为

Thermal Behavior of Zoledronic Acid Hydrate by TGA-MS and DSC-Microscopy(100)

7.21通过TGA-MS定量分析钴粉中的氧化钴

Quantification of Cobalt Oxide in a Coated Cobalt Powder by TGA-MS(103)

7.22通过TGA-GC/MS和TGA-Micro GC/MS研究聚酰胺66的分解产物

Investigation of Evolved Decomposition Products of Polyamide66

by TGA-GC/MS and TGA-Micro GC/MS(104)

7.23通过TGA-GC/MS、DSC和DMA鉴定多组分热塑性树脂

Identification of Multi-Component Thermoplastics by TGA-GC/MS, DSC and DMA(107)

7.24通过TGA-GC/MS、DSC、DMA和ATR研究橡胶的变形原因

Deformulation of a Rubber by TGA-GC/MS, DSC, DMA and ATR(113)

7.25通过TGA-GC/MS-FTIR测定聚丙烯材料有无磷酸铵阻燃剂的性质

Polypropylene with and without Ammonium Phosphate Flame Retardant

by TGA-GC/MS-FTIR(120)

7.26通过TGA-GC/MS对EPDM橡胶进行热氧化研究

Thermal Oxidation of EPDM Rubber by TGA-GC/MS(125)

7.27通过TGA-MS和TGA-GC/MS定量分析涂料中的二甲基甲酰胺（DMF）

Quantification of Dimethylformamide in Coatings by TGA-MS and TGA-GC/MS(129)

7.28TGA-GC/MS定量测定天然橡胶中低含量的丁苯橡胶

Quantification of a Low Content of Styrene-Butadiene Rubber in Natural Rubber

by TGA-GC/MS(134)

7.29通过TGA-Micro GC/MS技术分析酚醛树脂的分解产物

Evolved Decomposition Products of a Phenol-Formaldehyde Resin

by TGA-Micro GC/MS(137)

7.30通过TGA-Micro GC/MS技术定量分析焦炭样品中的二氧化碳

Quantification of Carbon Dioxide in a Coke Sample by TGA-Micro GC/MS(140)

7.31TGA-Micro GC/MS、TMA和DSC用于钛酸钡的合成和表征

Synthesis and Characterization of Barium Titanate by TGA-Micro GC/MS, TMA and DSC(142)

7.32用TGA-Micro GC/MS和Karl Fischer滴定仪测定热塑性塑料中的水含量

Determination of Water Content in a Thermoplastic by TGA-Micro GC/MS

and Karl Fischer titrator(147)

7.33通过TGA-GC/MS和TGA-Micro GC/MS研究生物质样品

Study of a Biomass Sample by TGA-GC/MS and TGA-Micro GC/MS(151)

7.34通过 TGA-GC/MS和TGA-Micro GC/MS分析由褐煤释放出的气体

Gases Evolved from Lignite by TGA-GC/MS and TGA-Micro GC/MS(157)

参考书目 Literature(164)

缩写和首字母缩写词 Abbreviations and Acronyms(165)